Rotational invariance and double frustration in the structures of gold clusters growing around the F(s)-defected MgO (100) surface.

Full Abstract

The interaction of small gold clusters (Au(n), n = 1-4, 20) and a gold monolayer with the MgO (100) surface surrounding a neutral oxygen vacancy (F(s) center) is investigated using density-functional (DF) calculations. It is found that the presence of the defect modifies the interaction of gold not only with the vacancy itself, but also with the oxygen and magnesium atoms around it by increasing both the adhesion energy and the equilibrium bond distances. This is at variance with the interaction of metal atoms with the regular MgO (100) surface or the F(s) defect itself, in which an increase of the adhesion energy is associated with a shortening of the metal-surface distance. The resulting double frustration and cylindrical invariance of the metal-surface interaction cause small gold clusters growing around an F(s) nucleation center to be highly fluxional in terms both of rotational freedom and of multiple competing structural motifs. Fragmentation energies of the gold clusters are also discussed, finding that the lowest-energy pathway corresponds to the detachment of a dimer.

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Author information

Author/s: Barcaro, Giovanni (G); Fortunelli, Alessandro (A);

Affiliation: Molecular Modeling Laboratory, Istituto per i Processi Chimico-Fisici, IPCF, del C.N.R., via G. Moruzzi 1, 56124, Pisa, Italy.

Journal and publication information

Publication Type: Journal Article

Journal: The journal of physical chemistry. B (J Phys Chem B), published in United States. (Language: eng)

Reference: 2006-Oct; vol 110 (issue 42) : pp 21021-7

Dates: Created 2006/10/19; Completed 2007/09/05;

PMID: 17048921, status: PubMed-not-MEDLINE (last retrieval date: 12/26/2008)

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