Research article summary (published 15 Jul 2009):

Copper(I)-catalyzed aryl bromides to form intermolecular and intramolecular carbon-oxygen bonds.

Full Abstract

A highly efficient Cu-catalyzed C-O bond-forming reaction of alcohol and aryl bromides has been developed. This transformation was realized through the use of copper(I) iodide as a catalyst, 8-hydroxyquinoline as a ligand, and K(3)PO(4) as a base. A variety of functionalized substrates were found to react under these reaction conditions to provide products in good to excellent yields.

Author information

Author/s: Niu, Jiajia (J); Guo, Pengran (P); Kang, Juntao (J); Li, Zhigang (Z); Xu, Jingwei (J); Hu, Shaojing (S);

Affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.

Journal and publication information

Publication Type: Journal Article; Research Support, Non-U.S. Gov't

Journal: The Journal of organic chemistry (J Org Chem), published in United States. (Language: eng)

Reference: 2009-Jul; vol 74 (issue 14) : pp 5075-8

Dates: Created 2009/07/10; Completed 2009/09/28;

PMID: 19476328, status: MEDLINE (last retrieved date: 9/28/2009)

Sourced from the National Library of Medicine. Abstract text and other information may be subject to copyright.

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MeSH headings (categories)

This article was linked to the MeSH Headings (categories) shown below.

Bromides - chemistry Carbon - chemistry Catalysis Copper - chemistry Ligands

Ligands Oxygen - chemistry Oxyquinoline - chemistry Phosphates - chemistry Potassium Compounds - chemistry

Note: Bold headings indicate primary MeSH headings or qualifiers.

Associated Chemicals: Bromides (0) ; Ligands (0) ; Phosphates (0) ; Potassium Compounds (0) ; Oxyquinoline (148-24-3) ; potassium phosphate (16068-46-5) ; Carbon (7440-44-0) ; Copper (7440-50-8) ; Oxygen (7782-44-7)

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